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“Copper” Is Never Just Copper

Writing “copper” on a drawing without a UNS designation is a procurement failure waiting to happen. The conductivity difference between C101 and C360 is 4×. The machinability difference between C110 and C360 is 5×. The cost difference can be 2–3×. This guide gives you the data to specify the right alloy the first time — with full property tables, machinability ratings, and exact drawing callout formats across the four alloys most commonly CNC machined.

Section 1 of 5

The UNS Copper Alloy Numbering System

The Unified Numbering System (UNS) is the authoritative designation for copper alloys in the United States. The first digit of the five-digit C-number encodes the alloy family directly. Conductivity throughout this guide is stated as % IACS — International Annealed Copper Standard — where 100% equals the conductivity of commercially pure annealed copper at 20°C (58.0 MS/m). Higher IACS means better electrical and thermal performance; lower IACS means conductivity has been traded for strength, machinability, or corrosion resistance.

C1xxxx

Coppers (≥99.3% Cu)

Pure coppers and silver-bearing coppers. Maximum electrical and thermal conductivity. Includes C10100 (OFHC), C11000 (ETP), C12200 (DHP — deoxidized, high phosphorus). Primary use: electrical conductors, bus bars, heat exchangers.

C2xxxx

Brasses (Cu-Zn)

Copper-zinc binary alloys. Zinc increases strength and reduces conductivity. C26000 (70/30 brass, cartridge brass) is the most common structural brass. Conductivity drops to ~27% IACS as zinc content rises.

C3xxxx

Leaded Brasses (Free-Machining)

Lead additions (1–4%) make chips discontinuous and dramatically improve machinability. C36000 (3% Pb) is the free-cutting brass reference standard at 100% machinability. The most economical copper alloy for high-volume CNC turning.

C5xxxx

Phosphor Bronzes (Cu-Sn-P)

Tin and phosphorus additions give high fatigue strength, excellent spring properties, and good corrosion resistance. C51000 (5% Sn) is used for springs and electrical contacts requiring flex life. Conductivity ~15% IACS.

C6xxxx

Aluminum & Silicon Bronzes

Aluminum bronzes (C63000, C63200) deliver the highest strength of any copper alloy — up to 110 ksi UTS — with excellent seawater corrosion resistance. Used for high-load bearings, marine hardware, and valve bodies.

C7xxxx

Copper-Nickels

Cu-Ni alloys (C70600: 10% Ni, C71500: 30% Ni) have outstanding seawater corrosion resistance and are used in marine heat exchangers and desalination hardware. Lower machinability than brasses; higher than pure copper.

Why CNC Shops Focus on C1xx and C3xx

The vast majority of copper CNC machining falls into two families: C1xx (pure coppers) for electrical performance and C3xx (leaded brasses) for machinability. C2xx brasses handle structural applications. The other families (bronzes, copper-nickels) are specialty alloys ordered for specific corrosion or mechanical requirements — not general-purpose machined parts.

Section 2 of 5

The Four Alloys You Will Actually Specify

Of the 400+ UNS copper alloys, four dominate CNC machining RFQs. Here is what distinguishes each one — technically, not vaguely.

CNC machined copper alloy parts: bus bars, heat sink fins, and electrical components
C101, C110, C260, and C360 are the most common alloys for CNC machining; choice depends on conductivity, machinability, and corrosion needs.

C10100 — OFHC Copper

99.99% Cu minimum, oxygen-free

101% IACS20% machinability

The highest-purity commercial copper. Oxygen is removed via vacuum or inert atmosphere casting, preventing Cu₂O grain-boundary films that cause hydrogen embrittlement when heated. Required for applications involving welding, brazing, or elevated-temperature service in hydrogen-containing atmospheres. Conductivity is slightly above the 100% IACS reference because the absence of oxygen removes a small conductivity-depressing impurity.

C11000 — ETP Copper

99.9% Cu minimum, electrolytic tough pitch

100% IACS20% machinability

The workhorse electrical copper. Produced by electrolytic refining, then cast with a controlled oxygen content (0.02–0.04% as Cu₂O inclusions). The oxygen does not materially affect conductivity at room temperature but makes the material susceptible to hydrogen embrittlement if heated above ~370°C in a hydrogen atmosphere. Widely stocked in flat bar, round rod, and sheet for bus bars and terminal blocks.

C26000 — Cartridge Brass

70% Cu / 30% Zn

28% IACS30% machinability

The standard structural brass. The 30% Zn content maximizes the alpha-phase ductility window, giving excellent cold-forming behavior (hence "cartridge" brass — it was the alloy for drawn ammunition cases). Machinability is only 30% — significantly worse than C360 — because the alpha-phase chips tend to be long and stringy. Use C26000 when forming or deep-drawing is required; use C36000 when high-volume machining is the primary operation.

C36000 — Free-Cutting Brass

61.5% Cu / 35.5% Zn / 3% Pb

26% IACS100% machinability

The machinability reference standard. The 3% lead addition is insoluble in the brass matrix and precipitates as fine globules at grain boundaries. Under cutting, lead acts as an internal lubricant and chip-breaker, producing short, discontinuous chips at high cutting speeds. At 100% machinability — C36000 is the reference standard for copper alloys, equivalent to B1112 free-machining steel on the general machinability scale — C360 can be turned at surface speeds of 200–400 sfm (61–122 m/min) with carbide tooling. The most cost-effective copper alloy for fittings, valves, and connectors.

Section 3 of 5

Copper Alloy Properties Comparison Table

All values for the most common CNC stock condition (annealed for C101/C110; half-hard H02 for C260/C360). Conductivity is at 20°C.

PropertyC10100 (OFHC)C11000 (ETP)C26000 (Brass)C36000 (Free-Cut)
Cu Content≥99.99%≥99.9%68.5–71.5%60.0–63.0%
Electrical Cond.101% IACS100% IACS27–28% IACS26% IACS
Thermal Cond.391 W/m·K388 W/m·K121 W/m·K115 W/m·K
UTS (half-hard)275 MPa (40 ksi)275 MPa (40 ksi)395 MPa (57 ksi)385 MPa (56 ksi)
Yield Strength69 MPa (10 ksi)69 MPa (10 ksi)310 MPa (45 ksi)130 MPa (19 ksi)
Elongation35%35%23%25%
Density8.89 g/cm³8.89 g/cm³8.53 g/cm³8.50 g/cm³
Machinability20%20%30%100% (reference)
Oxygen Content<0.0005%0.02–0.04%N/AN/A
Raw Cost (est.)Highest (~2.5×)High (~2×)Moderate (~1.3×)Baseline (1×)

* Machinability rated relative to AISI B1112 free-machining steel = 100%. Copper values from CDA (Copper Development Association) datasheets and ASM Handbook Vol. 2. UTS/yield for annealed temper (O60) for C101/C110; half-hard (H02) for C260/C360.

If you need

Maximum conductivity (>95% IACS)

C101 or C110

101% / 100% IACS — 3–4× the conductivity of any brass alloy.

If you need

High-volume machined parts

C360 (Free-Cut)

100% machinability — typically shortest cycle time and lowest machined part cost.

If you need

Structural brass with forming

C260 (Cartridge)

23% elongation in H02 — deep-drawing and bending capability that C360 cannot match.

If you need

Lead-free / RoHS compliance

C110 or C260

Both are lead-free. C360 contains 3% Pb and fails most RoHS product exemptions.

Machine Any of These Copper Alloys at MakerStage

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Section 4 of 5

Alloy Selection Decision Matrix

Start with C360 as your default for any machined copper part. Upgrade only when electrical performance, hydrogen embrittlement risk, or regulatory requirements demand it.

ApplicationRecommendedWhyAvoid
Bus bars, power distribution railsC110 (ETP)100% IACS conductivity, widely stocked in flat bar, lower cost than C101.C360 (26% IACS — 4× conductivity penalty for high-current applications)
Parts exposed to welding or brazingC101 (OFHC)Oxygen-free — no hydrogen embrittlement risk when heated in reducing atmosphere.C110 (ETP embrittles above ~370°C in H₂ atmosphere)
High-volume turned fittings, connectorsC360 (Free-Cut)100% machinability — typically the shortest cycle time and lowest part cost among copper alloys. Acceptable conductivity for non-critical paths.C110 (20% machinability — 5× more tool wear and cycle time for equivalent geometry)
Structural brass parts, deep-drawn componentsC260 (Cartridge)Superior cold-forming ductility (23% elongation in H02 temper). Better corrosion resistance than C360.C360 (lead content complicates forming, spring-back behavior)
RoHS / lead-free requirementC110 or C260Both are lead-free. C360 contains 3% Pb and fails RoHS exemptions for many product categories.C360 (3% Pb content)
Maximum thermal conductivity (heat sink, cold plate)C101 or C110391 / 388 W/m·K — more than 3× aluminum 6061. Justifies machining cost when thermal density is critical.C260 / C360 (121 / 115 W/m·K — closer to aluminum than to pure copper)

Decision Rule

If you need maximum conductivity: C110. If you need oxygen-free for brazing or welding: C101. If you need high-volume machined parts at typically lowest cost: C360. If you need structural brass with forming capability: C260. Do not default to C101 for bus bars — C110 delivers the same electrical performance at lower cost.

RoHS and Lead-Free Note

C360 contains 3% lead. RoHS Directive 2011/65/EU restricts lead to 0.1% max in electrical and electronic equipment. Some exemptions exist for copper alloys used in connectors, but verify applicability for your product category before specifying C360 in consumer electronics or medical devices.

Section 5 of 5

Drawing Callout Format

A drawing that says “copper” will get whatever the shop has in stock. Use the UNS designation and ASTM standard — this is a binding contractual specification.

C10100 — OFHC Copper

Copper, UNS C10100, ASTM B152 (sheet/strip) or B187 (rod/bar), Annealed (O61)

Add "Certify oxygen content ≤0.0005%" when embrittlement resistance must be verified. Required when parts will be brazed, welded, or used at elevated temperature in hydrogen-containing atmosphere.

C11000 — ETP Copper

Copper, UNS C11000, ASTM B187 (rod/bar) or B152 (sheet), Half-Hard (H02)

Half-Hard (H02) temper is the standard stock condition for machined bus bar and terminal stock. Specify "Annealed (O61)" if subsequent forming or crimping is required.

C26000 — Cartridge Brass

Brass, UNS C26000, ASTM B19 (strip) or B36 (sheet), Half-Hard (H02)

For drawn or formed parts, specify the final temper after forming. Do not call out C26000 for high-volume turning — cycle times will be significantly longer than equivalent C360 parts (30% vs. 100% machinability).

C36000 — Free-Cutting Brass

Brass, UNS C36000, ASTM B16 (rod/bar), Half-Hard

Half-Hard is the standard rod stock temper and is almost always what shops inventory. If your application requires RoHS compliance, C360 cannot be used — substitute C110 or C260.

Pro Tip: Temper Affects Machinability

For C110 and C101, specify Half-Hard (H02) or Hard (H04) when ordering rod for CNC turning — the work-hardened temper improves chip formation compared to fully annealed stock. Annealed pure copper galls tool faces aggressively; a harder temper reduces built-up edge and extends tool life. Ask your material supplier to confirm temper on the mill certificate.

Common Questions

Frequently Asked Questions

What is the most machinable copper alloy?
Copper C360 (free-cutting brass, UNS C36000) is the most machinable copper alloy, with a machinability rating of 100% — the reference standard against which all other metals are measured. The 3% lead addition creates short, discontinuous chips and reduces built-up edge on cutting tools. For comparison, pure copper (C110 or C101) rates only 20% due to its ductility and tendency to gall on tool faces.
What is the difference between OFHC copper and ETP copper?
OFHC (C101) is oxygen-free, high-conductivity copper with a minimum purity of 99.99% Cu and conductivity ≥101% IACS. ETP copper (C110) is electrolytic tough pitch with 99.9% Cu minimum, 100% IACS conductivity, and a small oxygen content (0.02–0.04% as Cu₂O). C101 is used where hydrogen embrittlement is a risk (welding, brazing, elevated temperature service); C110 is the standard choice for bus bars and electrical contacts where the oxygen content is not a concern.
What does the UNS number mean for copper alloys?
UNS (Unified Numbering System) copper alloys range from C10000 to C99999. The first digit encodes the alloy family: C1xxxx = coppers (≥99.3% Cu), C2xxxx = high-copper alloys and plain brasses, C3xxxx = leaded brasses, C4xxxx = tin brasses, C5xxxx = phosphor bronzes, C6xxxx = aluminum and silicon bronzes, C7xxxx = copper-nickels. The last four digits further identify the specific alloy within the family.
Can copper be CNC machined to tight tolerances?
Yes, but alloy choice is critical. C360 (free-cutting brass) machines cleanly to ±0.001 in (±0.025 mm) on turned diameters without difficulty. Pure copper grades (C101, C110) require sharp, polished carbide or PCD tooling, reduced cutting speeds, and increased coolant flow to achieve comparable tolerances — they are much more prone to built-up edge and smearing than brass. For tight-tolerance copper electrical parts, C110 is the standard; for tight-tolerance fittings and connectors, C360 is preferred.
What copper alloy should I use for a bus bar?
C110 (ETP copper, UNS C11000) is the standard for bus bars. It delivers 100% IACS conductivity, machines acceptably for bus bar profiles, and is widely stocked in flat bar and rod. For high-current applications where maximum conductivity is needed and hydrogen embrittlement risk exists (e.g., near welding or brazing), upgrade to C101 (OFHC). Avoid brass alloys (C260, C360) for bus bars — their zinc content reduces conductivity to 27–28% IACS, which is a significant derating for high-current applications.
How do I call out copper material on an engineering drawing?
Use the full UNS designation and ASTM standard. Example for ETP copper bar: "Copper, UNS C11000, ASTM B187, Half-Hard (H02)." For OFHC: "Copper, UNS C10100, ASTM B152." For free-cutting brass rod: "Brass, UNS C36000, ASTM B16, Half-Hard." Never write just "copper" or "brass" — the shop will substitute whatever is in stock, and conductivity, machinability, and mechanical properties vary significantly across alloys.

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