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When You Need C101: Exactly One Reason

Copper 101 (OFHC) is not a “premium” version of C110 — it is an insurance policy against hydrogen embrittlement. If your copper part will be brazed, welded, or used in a hydrogen-containing atmosphere above ~370°C, C101 is required. If it will not, C110 delivers essentially identical properties at lower cost. This guide gives you the complete data on C101: composition, properties, machinability, applications, and the exact drawing callout format to prevent substitution.

Section 1 of 5

Composition and Standards

Element / PropertySpecificationNotes
Copper (Cu)≥99.99% minHighest purity commercial grade — all other elements are trace
Oxygen (O)≤0.0005% (5 ppm)The defining property — no Cu₂O inclusions in microstructure
Silver (Ag)≤0.0025%Trace; does not affect conductivity at this level
All other elements≤0.0065% totalPer ASTM B170 cathode quality limits
UNS designationC10100Unified Numbering System
European equivalentEN CW008A (OF-Cu)DIN / EN standard designation
ASTM rod/barASTM B187Rod, bar, and shapes
ASTM sheet/stripASTM B152Sheet, strip, plate, and rolled bar
ASTM cathodeASTM B170Melt stock cathode grade
Common tempersO61 (Annealed), H02 (Half-Hard), H04 (Hard)H02 is standard for CNC bar stock
Section 2 of 5

Electrical, Thermal, and Mechanical Properties

PropertyValueCondition / Notes
Electrical conductivity101% IACS minimumAt 20°C; 5.84×10⁷ S/m
Electrical resistivity1.71 µΩ·cmAt 20°C
Thermal conductivity391 W/m·KAt 20°C — highest of any common engineering metal except silver
Density8.89 g/cm³
Specific heat385 J/kg·KAt 20°C
Coefficient of thermal expansion16.5 µm/m·°C20–300°C range
Melting point1,083°C (1,981°F)
UTS (Annealed O61)220 MPa (32 ksi)Annealed condition
UTS (Half-Hard H02)275 MPa (40 ksi)Standard bar stock condition
Yield strength (H02)250 MPa (36 ksi)0.5% extension under load
Elongation (H02)14%In 2 in gauge length
Hardness (H02)HRF 60 / HB 78
Machinability20%Vs. C36000 free-cutting brass = 100%

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Section 3 of 5

Machinability and CNC Parameters

Copper 101 is rated at 20% machinability relative to C36000 free-cutting brass. Key challenge: built-up edge and long chips require specific tooling and parameters.

Turning Parameters

Tool material:Uncoated carbide (K-grade) or PCD
Surface speed (carbide):200–350 sfm (61–107 m/min)
Feed rate:0.003–0.006 ipr
Depth of cut (finishing):0.005–0.010 in
Rake angle:+8° to +12° (positive rake required)
Coolant:Flood — 8–10% water-soluble

Design Tips for C101 Parts

Min wall thickness:0.040 in — avoid thin walls, copper deflects
Thread tapping:HSS spiral-point, sulphurized oil, 50–80 sfm (15–24 m/min)
Surface finish:Ra 32–63 µin (carbide); Ra 16 µin (PCD)
Workholding:Soft jaws — copper marks at HRB 60
Tolerances:±0.001 in turned OD; ±0.002 in milled features
Chips:Plan chip management — long continuous chips
Section 4 of 5

Common Applications

Brazed assemblies

Coils, manifolds, and heat exchanger tubes that will be silver-brazed or torch-brazed in air or reducing atmosphere. C110 would embrittle at the braze joint interface.

Vacuum feedthroughs

Electrical and fluid feedthroughs for vacuum chambers and electron beam equipment. The oxygen-free grade prevents outgassing of Cu₂O under vacuum bakeout conditions.

RF and coaxial conductors

Center conductors and shells for high-precision RF connectors and coaxial cable where minimal dielectric loss and no outgassing are required.

Induction heating components

Induction heating work coils and susceptors that are directly heated in hydrogen or mixed atmosphere furnaces for brazing or annealing operations.

High-vacuum electrical contacts

Contacts in vacuum interrupter switches, particle accelerator components, and synchrotron beamline hardware where Cu₂O microstructure is incompatible.

Medical and semiconductor equipment

Parts used in oxygen-sensitive process environments where Cu₂O inclusions could cause oxygen contamination or interfere with ultra-high-purity processes.

Section 5 of 5

Drawing Callout Format

Precision material callout prevents shop substitution of C110 for C101, which is the most common error in copper procurement.

Standard Rod/Bar (CNC Machining)

Copper, UNS C10100, ASTM B187 Temper: Half-Hard (H02) Note: OFHC copper required. ETP copper (UNS C11000) NOT acceptable.

The explicit rejection note for C110 is the most important part. Without it, the shop will substitute based on availability. Mill certificate (MTR) confirming C10100 and oxygen content ≤0.0005% should be required for critical applications.

Sheet/Strip (Formed or Cut Parts)

Copper, UNS C10100, ASTM B152 Temper: Annealed (O61)

Annealed temper for sheet/strip where forming, stamping, or deep drawing will be performed after machining. For applications requiring H02 temper in strip form, confirm with your material supplier — annealed strip is more commonly stocked.

Common Questions

Frequently Asked Questions

What is copper 101 (OFHC)?
Copper 101 (UNS C10100) is oxygen-free, high-conductivity (OFHC) copper with a minimum purity of 99.99% Cu and a minimum electrical conductivity of 101% IACS. It is produced by casting electrolytic copper in a vacuum or inert atmosphere to prevent oxygen pickup, resulting in a microstructure with no Cu₂O inclusions. The absence of oxygen makes it immune to hydrogen embrittlement — a failure mode that affects ETP copper (C110) when heated above ~370°C in hydrogen-containing atmospheres.
What is the electrical conductivity of copper 101?
Copper 101 has a minimum electrical conductivity of 101% IACS (International Annealed Copper Standard) at 20°C. The IACS reference was defined at 100% for a specific copper purity; C101 exceeds this slightly because the absence of dissolved oxygen removes a small conductivity-depressing impurity. In practice, the 1% conductivity difference between C101 (101% IACS) and C110 ETP copper (100% IACS) is not perceptible in most electrical applications.
What are the main applications for copper 101?
Copper 101 is used where hydrogen embrittlement resistance is required: components that will be silver-brazed, torch-brazed, or induction-heated in reducing atmospheres; vacuum envelope parts; coaxial cable conductors; high-vacuum electrical feedthroughs; particle accelerator components; and oxygen-sensitive medical device components. It is also specified in semiconductor equipment where oxygen contamination of the process environment is a concern.
Is copper 101 the same as C10100?
Yes. Copper 101 is the common commercial name. The UNS designation is C10100. ASTM designations include B170 (cathode quality), B152 (sheet and strip), and B187 (rod and bar). The O1 or OF suffix sometimes seen on European datasheets refers to the same oxygen-free copper family (EN CW008A). When writing a drawing callout, always use the UNS designation (C10100) with the relevant ASTM specification rather than the informal "Copper 101" trade name.
How does copper 101 compare to copper C110 for CNC machining?
Copper 101 and C110 (ETP copper) have essentially identical machinability, both rated at 20% relative to the C36000 free-cutting brass reference standard. Both produce long, continuous chips, are prone to built-up edge on tool faces, and require sharp, polished carbide or PCD tooling with flood coolant. Achievable tolerances (±0.001 in on turned ODs) and surface finish (Ra 32–63 µin with carbide) are the same. The oxygen content difference does not affect machining behavior.
What ASTM standard covers copper 101 rod and bar?
ASTM B187 covers copper rod and bar (including C10100). For sheet and strip, ASTM B152 applies. For cathode-quality OFHC copper (used in melt stock), ASTM B170 is the standard. When specifying on an engineering drawing, use: "Copper, UNS C10100, ASTM B187, [temper]" where temper is typically Half-Hard (H02) for machined bar stock.

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